It was probably too late (around 1996 to 97), but there was Smalltalk Express which was essentially Smalltalk/V for Windows that was released for free after ParcPlace and Digitalk merged. It never received any updates though and was only a Windows 3.1 program. It also came with a lengthy tutorial (actually a 16 chapter book) in HTML format.

Here it is running under Windows 10 (thanks to otvdm/winevdm that allows running 16bit programs in 64bit windows): https://i.imgur.com/r5aQNyJ.png