Eh. If they exchange one lawyer's time for $3.5 million in donations that will be used for all their other causes, that's actually a pretty good deal. (Or at least would be if Heard paid up, which she apparently didn't.)
I don't see a fundamental conflict between the ACLU's core beliefs and offering legal aid to a woman accusing her ex-husband of domestic violence. (Although I'll readily admit I don't see much reason for ACLU to get involved either.)